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Carbon Print by betty

A carbon print is a photographic print produced by soaking a carbon tissue in a dilute sensitizing solution of potassium dichromate. The solution also consists of carbon, gelatin, and a coloring agent. The process was created as a result of print fading in early photographic processes, and was patented in 1864 by Joseph Wilson Swan.

An Overview and History of Carbon (Pigment) Printing

The carbon process, initially a black and white process using lamp black (carbon black), was invented by Alphonse Poitevin in 1855. The process was later adapted to color, through the use of pigments, by Louis Arthur Ducos du Hauron in 1868. Carbon printing remained commercially popular through the first half of the 20th century. It was replaced over time by the dye-transfer process, chromogenic, dye-bleach (or dye destruction, i.e., Cibachrome) and, now, digital printing processes. The efficiencies gained through these more modern automated processes relegated carbon printing to the commercial backwaters in the latter half of the 20th century. It is now only found in the darkrooms of the rare enthusiast and a few exotic labs.

Carbon printing relies upon the ability of gelatin, when sensitized to light by a dichromate, to become insoluble in water after exposure to sunlight, or its modern equivalent (UV). Three successive layers of gelatin, containing first yellow, then magenta and finally cyan pigment, are, one at a time, exposed, aligned (registered) and then transferred onto a white opaque support (substrate, base or carrier, i.e., paper or melinex) and processed in warm water (100 F to 105 F). A fourth layer of black was added later on to improve density and mask any spurious color cast in the shadows. The unexposed areas, which remain soluble in warm water, are washed away, revealing, according to the inverse of the exposure, the underlying white support. This creates a bas-relief effect of varying texture and finish on the surface of the print that is the unique signature of the carbon process. Each color carbon print requires three, or four, round trips in the darkroom to create a finished color print (see CMYK). An individual, using existing pigmented sheets and separations, can prepare, print and process enough material, 60 sheets including the support, to produce about 12 – 20″ x 24″ four color prints in a 40 hour week.

It should be noted here that the carbon process is typically used to produce;

-Mono-chrome prints, usually B&W, but often sepia, cyan or any other preferred color.

-Duo-chrome (duo-tone) prints, an effect many printers are familiar with, using complementary or associated colors to their best effect.

-Tri-chrome prints, a traditional full color print made by layering Y, M & C pigment sheets.

-Quadra-chrome prints, basically the same full color print as the tri-chrome with the added finishing layer of black (K) to add density and mask spurious color in the shadows.

That noted, any combination of layers, in any color, are possible to achieve whatever ends the printer desires.

Its also important to mention here that there are two primary techniques used in carbon printing, single transfer and double transfer. This has to do with the negatives (separations) being right or wrong reading and the image “flopping” during the transfer process.

Because the carbon printing process uses pigments instead of dyes, it is capable of producing a far more archivally stable (permanent) print than any of the other color processes. Good examples of the color stability of pigments can be found in the paintings of the great masters, the true colors of which, in many cases, have survived all these centuries. A more contemporary example of the color stability of pigments is found in the paints used on automobiles today, which must survive intense daily exposure to very harsh lighting, under extreme conditions. The useful life of many (but not all) pigment formulations has been projected out to be several centuries and beyond (perhaps millennia, if cave paintings of Lascaux, the wall paintings in the tombs of the Valley of the Kings and the frescoes of Pompeii are relevant examples), often being limited only to the useful life of the particular support used. Additionally, the use of pigment also produces a wider color gamut than any of the other color processes, allowing for a greater range and subtlety of color reproduction.

Though carbon printing always has been, and remains, a labor intensive, time consuming and technologically demanding process, there are still those that prefer the high aesthetic of its remarkable beauty and longevity over all other processes.

Chronological History of Carbon (Pigment) Printing

Date

Name

Nationality

Remarks

1798

Louis Nicolas Vauquelin

French

Influence of the light on the silver chromate

1826

Joseph Nicphore Nipce

French

First picture in April 1826

1832

Gustav Suckow

French

Chromic acid salts are light sensitive, even without silver

1836

Sir John Frederick William Herschel

English

Invention of the word “photography”

1839

Mungo Ponton

English

Action of the light on paper coated with potassium dichromate + washing = fixed image

1840

Henri Becquerel

French

Action of the light on paper coated with potassium dichromate + iodine fumes = fixed image

1852

William Henry Fox Talbot

English

Insolubility of gelatin by potassium dichromate under influence of the light

1855

Louis Alphonse Poitevin

French

Inventor of photographic printing with dichromated pigment process

1858

L’abb Laborde

French

Principle of exposure through the base then transfer from one base to the other (see Fargier)

1860

Fargier

French

Principle of exposure through the base then transfer from one base to the other (see Laborde) but the imaged is reversed

1860

Blaise

French

Double transfer to get a non-reversed image

1861

James Clerk Maxwell

English

Principle of the trichrome separation influenced Louis Arthur Ducos du Hauron

1862

Louis Arthur Ducos du Hauron

French

Tricolor carbon process, see Charles Cros in 1867

1863

Pouncy

English

Uses sensitized inks

1863

Poitevin

French

Modification of his process: insolubility of the pigmented gelatin then solubility by exposure through a positive film

1864

Joseph Wilson Swan

English

Swan process: uses rubber for the transfer

1867

Charles Cros

French

Tricolor carbon process. See Louis Arthur Ducos du Hauron in 1862

1868

Marion

French

Procd Marion: Uses an albuminated paper for the transfer

1869

Jeanrenaud

French

Procd Jeanrenaud: Improvement of the transfer

1869

Jeanrenaud

French

Double transfer with an opal glass

1870

Gobert

French

1870-1873 printing on metal plates

1873

Marion

French

Mariotype

1874

Vogel

French

Principle of chromatic sensitization of the AgBr for the tricolor separation during the shot

1878

Louis Arthur Ducos du Hauron

French

Description of the heliochromie process

1878

Fredric Artigues

French

Charbon velours

1881

Charles Cros

French

Tricolor process presented to the “Academie des Sciences” (French Academy of Sciences)

1882

Charles Cros

French

Tricolor process. Bulletin de la Socit des Photographie

1889

Artigues

French

Papiers charbon velours

1893

Victor Artigues

French

Carbon velours tons continus de 1893 1910

1894

Ladeveze Rouille

French

Papier gomme-chrome

1899

T Manly

French

Ozotype derived from mariotype

1899

Henri Theodore Fresson

French

Procd Fresson: sold in USA between 1927 and 1939 by Edward Alenias. Bought by Luis Nadeau, Canada, 1979

1900

Fresson

French

Papier charbon Satin then papier Arvel to be processed with chlorine

1902

Robert Krayn

American

N.P.G. Process: tricolor carbon process distributed in France by La Socit Industrielle de Photographie

1906

T Manly

French

Ozobromie

1910

Arbuthnot

English

Dichromated watercolor or dichromated lavish

1911

Dovertype

English

Sold in England by the Dover Street Studio, London, 1911-1914

1913

S. Manners

American

Early form of three color carbro 1913-1922

1919

H.F. Farmer

English

Carbro process based on Manly’s ozobromie, Sold by Autotype in London

1920

H.F. Farmer

English

Carbro Tricolor 1920 to 1960 by Autotype

1923

H.J.C. Deeks

American

Raylo: three color carbon

1950

Kolorod

American

Dichromated colloid: carbon transfer process

1951

Pierre Fresson

French

Quadrichromie Fresson

1965

3M

American

3M Electrocolor Print 1965 to 1978

1977

Kwik-Print

American

Light Impressions Corp , Rochester

1982

Archival Color Co.

American

San Francisco: quad-color carbon process

1983

George Griffin

Canadian

Quad halftone, duotone and mono contone carbon until from 1983 to 2006 Private collection of photographers work only.

1985

Polaroid

American

Laser separation + transfer of pigment on a base. Stopped in 1986: Polaroid Permanent Pigment Print

1986

Jerry Kuska & Douglas Madeley

American & Canadian

Four color carbon prints, Limited Edition Photo/Graphics, Santa Cruz, California, until 1991

1993

Charles Berger

American

Ultrastable Color System. Pigmented quadrichromy

1998

Racey Gilbert

American

Ataraxia Pigment Prints, until 2004

2006

Tod Gangler

American

Art & Soul Photo, Seattle, Washington, Four color carbon prints and metallic quadtone black & white carbons

See also

Woodburytype, a variation of the carbon process

External links

Alternative Photography – Covering the Carbon Printing Process

Art & Soul Photo, Seattle, WA – Contemporary Color Carbon Printing Services

Bostick & Sullivan, Inc. – Carbon Printing Methods & Materials

Fresson, Paris, France – Carbon Printing Services for over a Century

Photographers Formulary – A Resource for many Historic & Alternative Photography Supplies

Categories: Photographic processes | Non-impact printing

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